Atmospheric Water Generation
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An atmospheric water generator (AWG), is a device that extracts water from
humid Humidity is the concentration of water vapor present in the air. Water vapor, the gaseous state of water, is generally invisible to the human eye. Humidity indicates the likelihood for precipitation, dew, or fog to be present. Humidity depen ...
ambient air, producing
potable water Drinking water is water that is used in drink or food preparation; potable water is water that is safe to be used as drinking water. The amount of drinking water required to maintain good health varies, and depends on physical activity level, ag ...
.
Water vapor (99.9839 °C) , - , Boiling point , , - , specific gas constant , 461.5 J/( kg·K) , - , Heat of vaporization , 2.27 MJ/kg , - , Heat capacity , 1.864 kJ/(kg·K) Water vapor, water vapour or aqueous vapor is the gaseous pha ...
in the air can be extracted by multiple techniques, including
condensation Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to ...
- cooling the air below its
dew point The dew point is the temperature to which air must be cooled to become saturated with water vapor, assuming constant air pressure and water content. When cooled below the dew point, moisture capacity is reduced and airborne water vapor will cond ...
, exposing the air to
desiccant A desiccant is a hygroscopic substance that is used to induce or sustain a state of dryness (desiccation) in its vicinity; it is the opposite of a humectant. Commonly encountered pre-packaged desiccants are solids that absorb water. Desiccant ...
s, using membranes that only pass water vapor, collecting fog, or pressurizing the air. AWGs are useful where potable water is difficult to obtain, because water is always present in ambient air. AWG may require significant energy inputs or operate passively, relying on natural
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...
differences.
Biomimicry Biomimetics or biomimicry is the emulation of the models, systems, and elements of nature for the purpose of solving complex human problems. The terms "biomimetics" and "biomimicry" are derived from grc, βίος (''bios''), life, and μίμησ ...
studies have shown the '' Stenocara gracilipes'' beetle has the natural ability to perform this task.


History

The
Incas The Inca Empire (also Quechuan and Aymaran spelling shift, known as the Incan Empire and the Inka Empire), called ''Tawantinsuyu'' by its subjects, (Quechuan languages, Quechua for the "Realm of the Four Parts",  "four parts together" ) wa ...
were able to sustain their culture above the rain line by collecting dew and channeling it to
cisterns A cistern (Middle English ', from Latin ', from ', "box", from Greek ', "basket") is a waterproof receptacle for holding liquids, usually water. Cisterns are often built to catch and store rainwater. Cisterns are distinguished from wells by t ...
for later distribution. Historical records indicate the use of water-collecting fog fences. These traditional methods have usually been completely passive, employing no external energy source and relying on naturally occurring temperature variations. Air wells are one way to passively collect moisture from air. Brine extraction technology was contracted by the US Army and the US Navy from Terralab and the
Federal Emergency Management Agency The Federal Emergency Management Agency (FEMA) is an agency of the United States Department of Homeland Security (DHS), initially created under President Jimmy Carter by Presidential Reorganization Plan No. 3 of 1978 and implemented by two Exec ...
(FEMA).
DARPA The Defense Advanced Research Projects Agency (DARPA) is a research and development agency of the United States Department of Defense responsible for the development of emerging technologies for use by the military. Originally known as the Adv ...
's Atmospheric Water Extraction program that aims to develop a device which can provide water for 150 soldiers and be carried by four people. In February 2021
General Electric General Electric Company (GE) is an American multinational conglomerate founded in 1892, and incorporated in New York state and headquartered in Boston. The company operated in sectors including healthcare, aviation, power, renewable energ ...
was awarded 14 million dollars to continue development of their device. In 2022, a
cellulose Cellulose is an organic compound with the formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell wall ...
/ konjac gum-based desiccant was demonstrated that produced 13 L/kg/day (1.56 US gal/lb/day) of water at 30% humidity, and 6 L/kg/day (0.72 US gal/lb/day) at 15% humidity.


Technologies

Cooling-based systems are the most common, while hygroscopic systems are showing promise. Hybrid systems combine
adsorption Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a f ...
, refrigeration and condensation.


Cooling condensation

Condensing systems are the most common technology in use. A cooling condensation type AWG uses a
compressor A compressor is a mechanical device that increases the pressure of a gas by reducing its volume. An air compressor is a specific type of gas compressor. Compressors are similar to pumps: both increase the pressure on a fluid and both can transp ...
to circulate
refrigerant A refrigerant is a working fluid used in the heat pump and refrigeration cycle, refrigeration cycle of air conditioning systems and heat pumps where in most cases they undergo a repeated phase transition from a liquid to a gas and back again. Ref ...
through a condenser and then an evaporator coil that cools the surrounding air. Once the air temperature reaches its
dew point The dew point is the temperature to which air must be cooled to become saturated with water vapor, assuming constant air pressure and water content. When cooled below the dew point, moisture capacity is reduced and airborne water vapor will cond ...
, water condenses into the collector. A fan pushes filtered air over the coil. A purification/filtration system keeps the water pure and reduces the risk posed by ambient microorganisms. The rate of water production depends on the ambient temperature, humidity, the volume of air passing over the coil, and the machine's capacity to cool the coil. AWGs become more effective as relative humidity and air temperature increase. As a rule of thumb, cooling condensation AWGs do not work efficiently when the ambient temperature falls below 18.3 °C (65 °F) or the relative humidity drops below 30%. The cost-effectiveness of an AWG depends on the capacity of the machine, local humidity and temperature conditions, and power costs. The
Peltier effect The thermoelectric effect is the direct conversion of temperature differences to electric voltage and vice versa via a thermocouple. A thermoelectric device creates a voltage when there is a different temperature on each side. Conversely, when ...
of semiconducting materials offer an alternative condensation system in which one side of the semi-conducting material heats while the other side cools. In this application, the air is forced over the cooling fans on the side that cools which lowers the air temperature. The solid-state semiconductors are convenient for portable units, but this is offset by low efficiency and high power consumption. Potable water generation can be enhanced in low humidity conditions by using an
evaporative cooler An evaporative cooler (also known as evaporative air conditioner, swamp cooler, swamp box, desert cooler and wet air cooler) is a device that cools air through the evaporation of water. Evaporative cooling differs from other air conditioning s ...
with a
brackish water Brackish water, sometimes termed brack water, is water occurring in a natural environment that has more salinity than freshwater, but not as much as seawater. It may result from mixing seawater (salt water) and fresh water together, as in estua ...
supply to increase the humidity. A special case is water generation in greenhouses because the inside air is much hotter and more humid. Examples include the
seawater greenhouse A seawater greenhouse is a greenhouse structure that enables the growth of crops and the production of fresh water in arid regions which constitute about one third of the earth's land area. This in response to the global water scarcity and peak ...
in
Oman Oman ( ; ar, عُمَان ' ), officially the Sultanate of Oman ( ar, سلْطنةُ عُمان ), is an Arabian country located in southwestern Asia. It is situated on the southeastern coast of the Arabian Peninsula, and spans the mouth of t ...
and the
IBTS Greenhouse The IBTS (“Integrated Biotectural System")-greenhouse is a biotectural, urban development project suited for hot arid deserts. It was part of the Egyptian strategy for the afforestation of desert lands from 2011 until spring of 2015, when geopol ...
. In dehumidifying
air conditioner Air conditioning, often abbreviated as A/C or AC, is the process of removing heat from an enclosed space to achieve a more comfortable interior environment (sometimes referred to as 'comfort cooling') and in some cases also strictly controlling ...
s, non-potable water is a by-product. The relatively cold (below the dewpoint) evaporator coil condenses water vapor from the processed air. When powered by coal-based electricity it has one of the worst
carbon footprint A carbon footprint is the total greenhouse gas (GHG) emissions caused by an individual, event, organization, service, place or product, expressed as carbon dioxide equivalent (CO2e). Greenhouse gases, including the carbon-containing gases carbo ...
s of any water source (exceeding
reverse osmosis Reverse osmosis (RO) is a water purification process that uses a partially permeable membrane to separate ions, unwanted molecules and larger particles from drinking water. In reverse osmosis, an applied pressure is used to overcome osmotic pre ...
seawater desalination by three
orders of magnitude An order of magnitude is an approximation of the logarithm of a value relative to some contextually understood reference value, usually 10, interpreted as the base of the logarithm and the representative of values of magnitude one. Logarithmic dis ...
) and it demands more than four times as much water up the supply chain than it delivers to the user.


Hygroscopy

Hygroscopic techniques pull water from the air via
absorption Absorption may refer to: Chemistry and biology * Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which ...
or
adsorption Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a f ...
. These materials desiccate the air. Desiccants may be liquid ("wet") or solid.


Wet desiccants

Liquid
desiccant A desiccant is a hygroscopic substance that is used to induce or sustain a state of dryness (desiccation) in its vicinity; it is the opposite of a humectant. Commonly encountered pre-packaged desiccants are solids that absorb water. Desiccant ...
s include
lithium chloride Lithium chloride is a chemical compound with the formula Li Cl. The salt is a typical ionic compound (with certain covalent characteristics), although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlor ...
or
lithium bromide Lithium bromide (LiBr) is a chemical compound of lithium and bromine. Its extreme hygroscopic character makes LiBr useful as a desiccant in certain air conditioning systems.Wietelmann, Ulrich and Bauer, Richard J. (2005) "Lithium and Lithium Compo ...
. Another wet desiccant is concentrated
brine Brine is a high-concentration solution of salt (NaCl) in water (H2O). In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawater, on the lower end of that of solutions used for br ...
. The brine absorbs water, which is then extracted and purified. One portable device runs on a
generator Generator may refer to: * Signal generator, electronic devices that generate repeating or non-repeating electronic signals * Electric generator, a device that converts mechanical energy to electrical energy. * Generator (circuit theory), an eleme ...
. Large versions, mounted on trailers, produce up to of water per day, at a ratio of up to 5 gallons of water per gallon of fuel. Another variation claims to be more environmentally friendly, by relying on
passive solar In passive solar building design, windows, walls, and floors are made to collect, store, reflect, and distribute solar energy, in the form of heat in the winter and reject solar heat in the summer. This is called passive solar design because, unli ...
energy and
gravity In physics, gravity () is a fundamental interaction which causes mutual attraction between all things with mass or energy. Gravity is, by far, the weakest of the four fundamental interactions, approximately 1038 times weaker than the stro ...
. Concentrated brine is streamed down the outside of towers, absorbing water vapor. The brine then enters a chamber, subjected to a partial
vacuum A vacuum is a space devoid of matter. The word is derived from the Latin adjective ''vacuus'' for "vacant" or "void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often dis ...
and heated, releasing water vapor that is condensed and collected. As the condensed water is removed from the system using gravity, it creates a vacuum which lowers the brine's boiling point.


Solid desiccants

Silica gel Silica gel is an amorphous and porous form of silicon dioxide (silica), consisting of an irregular tridimensional framework of alternating silicon and oxygen atoms with nanometer-scale voids and pores. The voids may contain water or some other l ...
and
zeolite Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These pos ...
desiccate pressurized air. Direct potable water generating devices using sunlight are under development. One device takes to make 1 liter of water. It uses a
zirconium Zirconium is a chemical element with the symbol Zr and atomic number 40. The name ''zirconium'' is taken from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian '' zargun'' (zircon; ''zar-gun'', ...
/organic metal-organic framework on a porous copper base, attached to a graphite substrate. The sun heats the graphite, releasing the water, which then cools the graphite.


Fuel cells

A hydrogen
fuel cell car A fuel cell vehicle (FCV) or fuel cell electric vehicle (FCEV) is an electric vehicle that uses a fuel cell, sometimes in combination with a small battery or supercapacitor, to power its onboard electric motor. Fuel cells in vehicles generate e ...
generates one liter of drinking quality water for every 8 miles (12.87 kilometers) traveled by combining hydrogen with ambient oxygen.


Power

Unless the air is super-saturated with vapor, an energy input is required to harvest water from the atmosphere. The energy required is a strong function of the humdity and temperature. It can be calculated using Gibbs free energy. Potable water can be generated by rooftop solar hydropanels using solar power and solar heat.
Hydrogel A hydrogel is a crosslinked hydrophilic polymer that does not dissolve in water. They are highly absorbent yet maintain well defined structures. These properties underpin several applications, especially in the biomedical area. Many hydrogels ar ...
s can be used to capture moisture (e.g. at night in a desert) to cool solar panels or to produce fresh water – including for irrigating crops as demonstrated in solar panel integrated systems where these have been enclosed next to or beneath the panels within the system. One study reported that such devices could help provide potable water to one billion people, although
off-the-grid Off-the-grid or off-grid is a characteristic of buildings and a lifestyle designed in an independent manner without reliance on one or more public utilities. The term "off-the-grid" traditionally refers to not being connected to the electrical gr ...
generation could "undermine efforts to develop permanent piped infrastructure".


See also

*
Air well (condenser) An air well or aerial well is a structure or device that collects water by promoting the condensation of moisture from air. Designs for air wells are many and varied, but the simplest designs are completely passive, require no external energy s ...
*
Dehumidifier A dehumidifier is an air conditioning device which reduces and maintains the level of humidity in the air. This is done usually for health or thermal comfort reasons, or to eliminate musty odor and to prevent the growth of mildew by extracting w ...
*
Desalination Desalination is a process that takes away mineral components from saline water. More generally, desalination refers to the removal of salts and minerals from a target substance, as in Soil salinity control, soil desalination, which is an issue f ...
*
Dew pond A dew pond is an artificial pond usually sited on the top of a hill, intended for watering livestock. Dew ponds are used in areas where a natural supply of surface water may not be readily available. The name dew pond (sometimes cloud pond or mist ...
*
Fog collection upright=1.3, ''Atrapanieblas'' or fog collection in Alto Patache, Atacama Desert, Chile">Atacama_Desert.html" ;"title="Alto Patache, Atacama Desert">Alto Patache, Atacama Desert, Chile Fog collection is the harvesting of water from fog using ...
*
Rainwater harvesting Rainwater harvesting (RWH) is the collection and storage of rain, rather than allowing it to run off. Rainwater is collected from a roof-like surface and redirected to a tank, cistern, deep pit (well, shaft, or borehole), aquifer, or a reservoir w ...
*
Solar chimney :''This article refers to a device for ventilation. For the power generation technology, see Solar updraft tower.'' A solar chimney often referred to as a thermal chimney is a way of improving the natural ventilation of buildings by using convecti ...
*
Solar still A solar still distills water with substances dissolved in it by using the heat of the Sun to evaporate water so that it may be cooled and collected, thereby purifying it. They are used in areas where drinking water is unavailable, so that cle ...
* Watergen * Watermaker *
Water scarcity Water scarcity (closely related to water stress or water crisis) is the lack of fresh water Water resources, resources to meet the standard water demand. There are two types of water scarcity: physical or economic water scarcity. Physical water ...


References

{{DEFAULTSORT:Atmospheric Water Generator Drinking water Water supply Water and the environment